Langmuir-Blodgett Instruments  Tensiometers  Goniometers  Surface Chemistry

KSV Sigma703


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Sigma 703 - Digital Tensiometer
Sigma 703 is manually operated all-round tensiometer and it measures surface or interfacial tensions of liquids by Du-Nouy or Wilhelmy plate method. The instrument is designed to be used in industrial, educational and other multiple user applications where a need for a tensiometer is occasional, work load is low or the purchase budget is limited. Sigma's features large digital read out with display memory and the ring correction values are automatically calculated. Measuring range is 0 to 200 mN/m and accuracy 0.1 mN/m.

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Features:

  • easy to use and sturdy construction
  • uses Du-Nouy or Wilhelmy plate method
  • large digital readout
  • automatic calculation of ring correction values
  • accurate electronic micro balance

Performance:

  • surface and interfacial tension measurement of liquids
  • absorption measurements

Specifications:

Maximum sample weight 25 g
Measuring range 0-250 mN/m (0-250 dyne/cm)
Resolution 0.1 mN
Stage operation manual precision lift stage
Vessel size 70 mm or 50 mm diameter

Accessories:

T201 Thermostatic vessel for temperature control of the sample liquid. A heat exchange vessel with water jacket type of construction. Heating/cooling of the water jacket by external bath/circulator. Fits glass sample vessels of 50 mm and 70 mm in diameter (T104, T105.) Operable temperature range 0 to +80 C. (External bath/circulator not included).
T104 Sample Vessel fireproof, diameter 70 mm, 5 pcs/box
T105 Sample Vessel fireproof, diameter 50 mm, 5 pcs/box
T106 Du Nouy ring Pt-Ir-ring made to DIN 53914-80 and ASTM D 971 specifications. Packed in wooden box.
T107 Wilhelmy Plate, platinum plate with micro roughened surface
T108 Ring re-form tool for straightening of disformed Du Nouy ring.
T109 Sample holder for plates. For rigid plate like samples. Max. sample thickness 3 mm.
T110 Sample holder for plates. For flexible plate like samples. Max. sample thickness 3 mm.
T111 Sample holder for fibres. Single use aluminium tube hanged from balance hook. 10 pcs/bag.

Catalogue summary
Applications
surfactants, soaps detergents

emulsions

Pharmaceuticals

Paints&Coatings

Paper, Film & ink products

Cosmetics

Oils, lubricants,

Designed to be used in industrial, educational and other multiple user applications, Sigma 703 offers a cost effective and accurate solution to routine measurement of surface and interfacial tension of liquids. Its straight forward operation and sturdy construction makes it so easy to use that even the inexperienced user can successfully make accurate measurement.


What is surface tension?
Surface tension is the property of a liquid in contact with air that makes it behave as if it was covered with a thin membrane under tension. The molecule inside the liquid interact equally with other molecules, from all sides, whereas the molecule at the surface is affected only by the molecule below it. Therefore the molecules exposed to air behave differently and try to contract to the smallest possible area. Surface tension is defined as the force acting over the surface of the liquid per unit length of the surface perpendicular to the force.

Why measure surface tension?

Understanding the interactions in-between the surfaces plays vital role in research of new surface-engineered materials and in development of products and processes with better performance. With today's sophisticated surface engineering technologies it is possible to modify nearly any liquid or solid surface to fit an application.
Surface tension is an extremely sensitive indicator providing information on the washability, wetting, emulsification, foaming and other surface related processes. The progress of various chemical reactions and presence of solvents or surfactants in a liquid systems can be monitored by surface tension measurement. Surface tension also provides information about the quality of water-repellent finishes, stability of emulsions, oxidation, polymerization etc.

For example; in the development of new detergents the measurement of surface tension becomes a indispensable tool in optimizing the performance of the detergent. Wetting of solids, for example textiles, becomes problematic when the surface tension of the water is high. The cleaning power is weak if the water can not penetrate deep into the structure of the fabric. The function of detergent is to lower the surface tension of the water detergent solution and to help the solution to thoroughly enter into the textile.



How to measure surface tension

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Du Nouy ring method


The most common way of measuring the surface tension is with the Du Nouy ring method. The method is named after the French physicist who developed it in the late 1800's. The measurement is performed by a Tensiometer, an instrument incorporating a precision micro balance, platinum-iridium ring with defined geometry and a precision mechanism to vertically move sample liquid in a glass beaker.

The ring hanging from the balance hook is first immersed into the liquid and then carefully pulled up, by lowering the sample cup, trough the surface of the liquid. The micro balance is recording on-line the force applied on the ring while pulling through the surface. The surface tension is the maximum force needed to detach the ring from the liquid surface.



Wilhelmy Plate method


The Wilhelmy plate method uses the same hardware as the ring method. In the dynamic plate method the platinum-iridium plate with defined perimeter is hung from the micro balance and the plate is immersed into the sample liquid. The surface of the plate is micro roughened in order to give it optimum wetting properties. The plate then is pulled through the surface of the liquid until the maximum force is reached and the plate brakes away from the surface.
      In the static plate method the dry unwetted plate is lowered to the surface until its lower edge nearly touches the surface. At this point the liquid "jumps" onto the edge and sides of the plate. The liquid wets the plate perimeter and increases its total mass to some maximum point which is proportional to the surface tension of the liquid.

Easy operation
The result of the measurement is displayed in large digit in the front panel. The tarring knob is used to zero the instrument before measurement. The Sigma 703 is factory calibrated and there is no need to calibrate balance before use. Ring or Wilhelmy plate measuring method is chosen from a mode selector.
    The measuring probe either the ring or plate is lifted from the liquid by manually lowering the measuring cup. A precision thumb wheel provides steady vertical movement of the sample vessel.


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